Rectification effects in coherent transport through single molecules
نویسندگان
چکیده
A minimal model for coherent transport through a donor/acceptor molecular junction is presented. The two donor and acceptor sites are described by single levels energetically separated by an intramolecular tunnel barrier. In the limit of strong coupling to the electrodes a current rectification for different bias voltage polarities occurs. Contacts with recent experiments of molecular rectification are also given. 2007 Elsevier B.V. All rights reserved.
منابع مشابه
1 6 N ov 2 00 6 Rectification effects in coherent transport through single molecules
A minimal model for coherent transport through a donor/acceptor molecular junction is presented. The two donor and acceptor sites are described by single levels energetically separated by an intramolecular tunnel barrier. In the limit of strong coupling to the electrodes a current rectification for different bias voltage polarities occurs. Contacts with recent experiments of molecular rectifica...
متن کاملTransport of a Liquid Water-Methanol Mixture in a Single Wall Carbon Nanotube
In this work, a molecular dynamics simulation of the transport of water - methanol mixture through the single wall carbon nanotube (SWCNT) is reported. Methanol and water are selected as fluid molecules since water represents a strongly polar molecule while methanol is as an intermediate between polar and strongly polar molecules. Some physical properties of the methanol-water mixture such as r...
متن کاملCoherent Transport of Single Photon in a Quantum Super-cavity with Mirrors Composed of Λ-Type Three-level Atomic Ensembles
In this paper, we study the coherent transport of single photon in a coupled resonator waveguide (CRW) where two threelevel Λ-type atomic ensembles are embedded in two separate cavities. We show that it is possible to control the photon transmission and reflection coefficients by using classical control fields. In particular, we find that the total photon transmission and reflection are achieva...
متن کاملPair Tunneling through Single Molecules.
By a polaronic energy shift, the effective charging energy of molecules can become negative, favoring ground states with even numbers of electrons. Here we show that charge transport through such molecules near ground-state degeneracies is dominated by tunneling of electron pairs which coexists with (featureless) single-electron cotunneling. Because of the restricted phase space for pair tunnel...
متن کاملMolecular junctions in the Coulomb blockade regime: Rectification and nesting
Quantum transport through single molecules is very sensitive to the strength of the molecule-electrode contact. Here, we investigate the behavior of a model molecular junction weakly coupled to external electrodes in the case where charging effects do play an important role Coulomb blockade regime . As a minimal model, we consider a molecular junction with two spatially separated donor and acce...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2007